@article{60661c88ee4e4d3a9f4ed581140e40ea,
title = "Carbon Dioxide Solubilities in Decanoic Acid-Based Hydrophobic Deep Eutectic Solvents",
abstract = "The solubility of CO2 in hydrophobic deep eutectic solvents (DESs) has been measured for the first time. Six different hydrophobic DESs are studied in the temperature range from 298 to 323 K and at CO2 pressures up to 2 MPa. The results are evaluated by comparing the solubility data with existing hydrophilic DESs and currently applied physical solvents and fluorinated ionic liquids. The DESs are prepared by mixing decanoic acid with a quaternary ammonium salt with different halide anions and alkyl chain lengths. The measured CO2 solubilities are similar to those found in renowned fluorinated ILs, while the heats of CO2 absorption are in the range of nonpolar solvents. The presented DESs show good potential to be used as CO2 capture agents.",
author = "Zubeir, {Lawien F.} and {Van Osch}, {Dannie J.G.P.} and Rocha, {Marisa A.A.} and Fawzi Banat and Kroon, {Maaike C.}",
note = "Funding Information: *E-mail:
[email protected]. ORCID Lawien F. Zubeir: 0000-0002-2295-306X Fawzi Banat: 0000-0002-7646-5918 Maaike C. Kroon: 0000-0002-5985-986X Present Address ⊥M.A.A.R.: NALCO Water, An Ecolab Company. Ir. G. Tjalmaweg 1, 2342 BV Oegstgeest, The Netherlands. Author Contributions #L.F.Z. and D.J.G.P.v.O. contributed equally. Funding Lawien Zubeir and Marisa Rocha gratefully acknowledged the financial support from the European Union 7th Framework project “IOLICAP” (Grant Agreement No. 283077). Dannie van Osch would like to thank the members of the ISPT {\textquoteleft}{\textquoteleft}Deep Eutectic Solvents in the Pulp and Paper Industry{\textquoteright}{\textquoteright} consortium for their financial and in kind contribution. Furthermore, this project received funding from the Bio-Based Industries Joint Undertaking under the European Union{\textquoteright}s Horizon 2020 research and innovation programme under grant agreement Provides No. 668970. Maaike Kroon and Fawzi Banat also would like to acknowledge financial support from the Gas Research Center (GRC) in Abu Dhabi (Project No. GRC11006). Notes The authors declare no competing financial interest. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = apr,
day = "12",
doi = "10.1021/acs.jced.7b00534",
language = "British English",
volume = "63",
pages = "913--919",
journal = "Journal of Chemical and Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "4",
}