Behavior of a deactivating HZSM-5 with varying Al3+ content in vapor phase aminocyclization

Kuppi Suresh Kumar Reddy; Inkollu Sreedhar; Sreerangam Venkateshwar; Kondapuram Vijay Raghavan

doi:10.1007/s10562-008-9522-5

Behavior of a deactivating HZSM-5 with varying Al³⁺ content in vapor phase aminocyclization

Kuppi Suresh Kumar Reddy, Inkollu Sreedhar, Sreerangam Venkateshwar, Kondapuram Vijay Raghavan

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Aminocyclization of aldehydes to synthesize pyridine bases is an interesting reaction with HZSM-5 catalyst undergoing rapid deactivation. The catalyst characterization studies like NH₃-TPD, XRD, TGA/DTA, Pore size distribution, SEM, CHNS, IR for the fresh and deactivated catalyst at various Si/Al ratio content as evidenced by the striking difference in the behavior of HZSM-5 catalyst in terms of its physicochemical characteristics, coke formation tendencies and higher selectivity to pyridine formation.

Original language	British English
Pages (from-to)	110-115
Number of pages	6
Journal	Catalysis Letters
Volume	125
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-008-9522-5
State	Published - Sep 2008

Keywords

Aminocyclization
CHNS
IR
NH-TPD
Pore size distribution
Pyridine synthesis
SEM
TGA/DTA
XRD

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10.1007/s10562-008-9522-5

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title = "Behavior of a deactivating HZSM-5 with varying Al3+ content in vapor phase aminocyclization",

abstract = "Aminocyclization of aldehydes to synthesize pyridine bases is an interesting reaction with HZSM-5 catalyst undergoing rapid deactivation. The catalyst characterization studies like NH3-TPD, XRD, TGA/DTA, Pore size distribution, SEM, CHNS, IR for the fresh and deactivated catalyst at various Si/Al ratio content as evidenced by the striking difference in the behavior of HZSM-5 catalyst in terms of its physicochemical characteristics, coke formation tendencies and higher selectivity to pyridine formation.",

keywords = "Aminocyclization, CHNS, IR, NH-TPD, Pore size distribution, Pyridine synthesis, SEM, TGA/DTA, XRD",

author = "{Suresh Kumar Reddy}, Kuppi and Inkollu Sreedhar and Sreerangam Venkateshwar and Raghavan, {Kondapuram Vijay}",

note = "Funding Information: Acknowledgements K. Suresh Kumar Reddy is thankful to CSIR, New Delhi for the award of SRF-GATE Fellowship.",

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doi = "10.1007/s10562-008-9522-5",

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AU - Suresh Kumar Reddy, Kuppi

AU - Sreedhar, Inkollu

AU - Venkateshwar, Sreerangam

AU - Raghavan, Kondapuram Vijay

N1 - Funding Information: Acknowledgements K. Suresh Kumar Reddy is thankful to CSIR, New Delhi for the award of SRF-GATE Fellowship.

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Y1 - 2008/9

N2 - Aminocyclization of aldehydes to synthesize pyridine bases is an interesting reaction with HZSM-5 catalyst undergoing rapid deactivation. The catalyst characterization studies like NH3-TPD, XRD, TGA/DTA, Pore size distribution, SEM, CHNS, IR for the fresh and deactivated catalyst at various Si/Al ratio content as evidenced by the striking difference in the behavior of HZSM-5 catalyst in terms of its physicochemical characteristics, coke formation tendencies and higher selectivity to pyridine formation.

AB - Aminocyclization of aldehydes to synthesize pyridine bases is an interesting reaction with HZSM-5 catalyst undergoing rapid deactivation. The catalyst characterization studies like NH3-TPD, XRD, TGA/DTA, Pore size distribution, SEM, CHNS, IR for the fresh and deactivated catalyst at various Si/Al ratio content as evidenced by the striking difference in the behavior of HZSM-5 catalyst in terms of its physicochemical characteristics, coke formation tendencies and higher selectivity to pyridine formation.

KW - Aminocyclization

KW - CHNS

KW - IR

KW - NH-TPD

KW - Pore size distribution

KW - Pyridine synthesis

KW - SEM

KW - TGA/DTA

KW - XRD

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DO - 10.1007/s10562-008-9522-5

M3 - Article

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SP - 110

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JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

Behavior of a deactivating HZSM-5 with varying Al³⁺ content in vapor phase aminocyclization

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Keywords

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