Adsorption of hydrogen sulfide at low temperatures using an industrial molecular sieve: An experimental and theoretical study

In the work presented herein, a joint experimental and theoretical approach has been carried out to obtain an insight into the desulfurization performance of an industrial molecular sieve (IMS), resembling a zeolitic structure with a morphology of cubic crystallites and a high surface area of 590 m² g⁻¹, with a view to removing H₂S from biogas. The impact of temperature, H₂S inlet concentration, gas matrix, and regeneration cycles on the desulfurization performance of the IMS was thoroughly probed. The adsorption equilibrium, sorption kinetics, and thermodynamics were also examined. Experimental results showed that the relationship between H₂S uptake and temperature increase was inversely proportional. Higher H₂S initial concentrations led to lower breakpoints. The presence of CO₂ negatively affected the desulfurization performance. The IMS was fully regenerated after 15 adsorption/desorption cycles. Theoretical studies revealed that the Langmuir isotherm better described the sorption behavior, pore diffusion was the controlling step of the process (Bangham model), and that the activation energy was 42.7 kJ mol⁻¹ (physisorption). Finally, the thermodynamic studies confirmed that physisorption predominated.