A sunlight-responsive metal–organic framework system for sustainable water desalination

Ranwen Ou, Huacheng Zhang, Vinh X. Truong, Lian Zhang, Hanaa M. Hegab, Li Han, Jue Hou, Xiwang Zhang, Ana Deletic, Lei Jiang, George P. Simon, Huanting Wang

Research output: Contribution to journalArticlepeer-review

129 Scopus citations

Abstract

Light-responsive materials with high adsorption capacity and sunlight-triggered regenerability are highly desired for their low-cost and environmentally friendly industrial separation processes. Here we report a poly(spiropyran acrylate) (PSP) functionalized metal–organic framework (MOF) as a sunlight-regenerable ion adsorbent for sustainable water desalination. Under dark conditions, the zwitterionic isomer quickly adsorbs multiple cations and anions from water within 30 minutes, with high ion adsorption loadings of up to 2.88 mmol g−1 of NaCl. With sunlight illumination, the neutral isomer rapidly releases these adsorbed salts within 4 minutes. Single-column desalination experiments demonstrated that PSP–MOF works efficiently for water desalination. A freshwater yield of 139.5 l kg−1 d−1 and a low energy consumption of 0.11 Wh l−1 would be reached for desalinating 2,233 ppm synthetic brackish water. Importantly, this adsorbent shows excellent stability and cycling performance. This work opens up a new direction for designing stimuli-responsive materials for energy-efficient and sustainable desalination and water purification.

Original languageBritish English
Pages (from-to)1052-1058
Number of pages7
JournalNature Sustainability
Volume3
Issue number12
DOIs
StatePublished - Dec 2020

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