A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes

Anna Pintus; Cristian Pilloni; Gabriele Pippia; Enrico Podda; M. Carla Aragoni; Vito Lippolis; Panagiotis Aloukos; Dionysios Potamianos; Nikolaos Chazapis; Stelios Couris; George C. Anyfantis; Alexandra M.Z. Slawin; J. Derek Woollins; Massimiliano Arca

doi:10.1039/d3dt00931a

A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes

Anna Pintus, Cristian Pilloni, Gabriele Pippia, Enrico Podda, M. Carla Aragoni, Vito Lippolis, Panagiotis Aloukos, Dionysios Potamianos, Nikolaos Chazapis, Stelios Couris, George C. Anyfantis, Alexandra M.Z. Slawin, J. Derek Woollins, Massimiliano Arca

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The third-order nonlinear optical (NLO) properties of a series of platinum diimine-dithiolate complexes [Pt(N^N)(S^S)] were investigated by means of Z-scan measurements, revealing second hyperpolarizability values up to 10⁻²⁹ esu, saturable absorption properties, and nonlinear refractive behaviour, which were rationalized also by means of DFT calculations.

Original language	British English
Pages (from-to)	9423-9432
Number of pages	10
Journal	Dalton Transactions
Volume	52
Issue number	27
DOIs	https://doi.org/10.1039/d3dt00931a
State	Published - 26 Jun 2023

Access to Document

10.1039/d3dt00931a

Cite this

Pintus, A., Pilloni, C., Pippia, G., Podda, E., Carla Aragoni, M., Lippolis, V., Aloukos, P., Potamianos, D., Chazapis, N., Couris, S., Anyfantis, G. C., Slawin, A. M. Z., Woollins, J. D., & Arca, M. (2023). A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes. Dalton Transactions, 52(27), 9423-9432. https://doi.org/10.1039/d3dt00931a

@article{6a9df8f22afb434bb24cccc237a970b4,

title = "A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes",

abstract = "The third-order nonlinear optical (NLO) properties of a series of platinum diimine-dithiolate complexes [Pt(N^N)(S^S)] were investigated by means of Z-scan measurements, revealing second hyperpolarizability values up to 10−29 esu, saturable absorption properties, and nonlinear refractive behaviour, which were rationalized also by means of DFT calculations.",

author = "Anna Pintus and Cristian Pilloni and Gabriele Pippia and Enrico Podda and {Carla Aragoni}, M. and Vito Lippolis and Panagiotis Aloukos and Dionysios Potamianos and Nikolaos Chazapis and Stelios Couris and Anyfantis, {George C.} and Slawin, {Alexandra M.Z.} and Woollins, {J. Derek} and Massimiliano Arca",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = jun,

day = "26",

doi = "10.1039/d3dt00931a",

language = "British English",

volume = "52",

pages = "9423--9432",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "27",

}

Pintus, A, Pilloni, C, Pippia, G, Podda, E, Carla Aragoni, M, Lippolis, V, Aloukos, P, Potamianos, D, Chazapis, N, Couris, S, Anyfantis, GC, Slawin, AMZ, Woollins, JD & Arca, M 2023, 'A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes', Dalton Transactions, vol. 52, no. 27, pp. 9423-9432. https://doi.org/10.1039/d3dt00931a

A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes. / Pintus, Anna; Pilloni, Cristian; Pippia, Gabriele et al.
In: Dalton Transactions, Vol. 52, No. 27, 26.06.2023, p. 9423-9432.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A new class of third-order nonlinear optical materials

T2 - laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes

AU - Pintus, Anna

AU - Pilloni, Cristian

AU - Pippia, Gabriele

AU - Podda, Enrico

AU - Carla Aragoni, M.

AU - Lippolis, Vito

AU - Aloukos, Panagiotis

AU - Potamianos, Dionysios

AU - Chazapis, Nikolaos

AU - Couris, Stelios

AU - Anyfantis, George C.

AU - Slawin, Alexandra M.Z.

AU - Woollins, J. Derek

AU - Arca, Massimiliano

PY - 2023/6/26

Y1 - 2023/6/26

N2 - The third-order nonlinear optical (NLO) properties of a series of platinum diimine-dithiolate complexes [Pt(N^N)(S^S)] were investigated by means of Z-scan measurements, revealing second hyperpolarizability values up to 10−29 esu, saturable absorption properties, and nonlinear refractive behaviour, which were rationalized also by means of DFT calculations.

AB - The third-order nonlinear optical (NLO) properties of a series of platinum diimine-dithiolate complexes [Pt(N^N)(S^S)] were investigated by means of Z-scan measurements, revealing second hyperpolarizability values up to 10−29 esu, saturable absorption properties, and nonlinear refractive behaviour, which were rationalized also by means of DFT calculations.

UR - http://www.scopus.com/inward/record.url?scp=85164280368&partnerID=8YFLogxK

U2 - 10.1039/d3dt00931a

DO - 10.1039/d3dt00931a

M3 - Article

C2 - 37358422

AN - SCOPUS:85164280368

SN - 1477-9226

VL - 52

SP - 9423

EP - 9432

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

A new class of third-order nonlinear optical materials: laser pulse-duration dependant saturable absorption and nonlinear refraction in platinum(ii) diimine-dithiolate complexes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this