A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

Akshaya K. Samal; Haibo Zhu; Moussab Harb; Shiv Shankar Sangaru; Dalaver H. Anjum; Mohamed N. Hedhili; Youssef Saih; Jean Marie Basset

doi:10.1039/c6cy02187e

A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

Akshaya K. Samal
, Haibo Zhu
, Moussab Harb
, Shiv Shankar Sangaru
, Dalaver H. Anjum
, Mohamed N. Hedhili
, Youssef Saih
, Jean Marie Basset

Physics

King Abdullah University of Science and Technology

Research output: Contribution to journal › Review article › peer-review

12 Scopus citations

Abstract

A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

Original language	British English
Pages (from-to)	581-586
Number of pages	6
Journal	Catalysis Science and Technology
Volume	7
Issue number	3
DOIs	https://doi.org/10.1039/c6cy02187e
State	Published - 2017

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title = "A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh \& Ir) catalysts for efficient hydrogenolysis of ester",

abstract = "A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.",

author = "Samal, \{Akshaya K.\} and Haibo Zhu and Moussab Harb and Sangaru, \{Shiv Shankar\} and Anjum, \{Dalaver H.\} and Hedhili, \{Mohamed N.\} and Youssef Saih and Basset, \{Jean Marie\}",

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year = "2017",

doi = "10.1039/c6cy02187e",

language = "British English",

volume = "7",

pages = "581--586",

journal = "Catalysis Science and Technology",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

AU - Samal, Akshaya K.

AU - Zhu, Haibo

AU - Harb, Moussab

AU - Sangaru, Shiv Shankar

AU - Anjum, Dalaver H.

AU - Hedhili, Mohamed N.

AU - Saih, Youssef

AU - Basset, Jean Marie

PY - 2017

Y1 - 2017

N2 - A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

AB - A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

UR - https://www.scopus.com/pages/publications/85026654497

U2 - 10.1039/c6cy02187e

DO - 10.1039/c6cy02187e

M3 - Review article

AN - SCOPUS:85026654497

SN - 2044-4753

VL - 7

SP - 581

EP - 586

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 3

ER -

A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

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