A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

Akshaya K. Samal; Haibo Zhu; Moussab Harb; Shiv Shankar Sangaru; Dalaver H. Anjum; Mohamed N. Hedhili; Youssef Saih; Jean Marie Basset

doi:10.1039/c6cy02187e

A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

Akshaya K. Samal, Haibo Zhu, Moussab Harb, Shiv Shankar Sangaru, Dalaver H. Anjum, Mohamed N. Hedhili, Youssef Saih, Jean Marie Basset

Physics

King Abdullah University of Science and Technology

Research output: Contribution to journal › Review article › peer-review

7 Scopus citations

Abstract

A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

Original language	British English
Pages (from-to)	581-586
Number of pages	6
Journal	Catalysis Science and Technology
Volume	7
Issue number	3
DOIs	https://doi.org/10.1039/c6cy02187e
State	Published - 2017

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10.1039/c6cy02187e

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title = "A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester",

abstract = "A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.",

author = "Samal, {Akshaya K.} and Haibo Zhu and Moussab Harb and Sangaru, {Shiv Shankar} and Anjum, {Dalaver H.} and Hedhili, {Mohamed N.} and Youssef Saih and Basset, {Jean Marie}",

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year = "2017",

doi = "10.1039/c6cy02187e",

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volume = "7",

pages = "581--586",

journal = "Catalysis Science and Technology",

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T1 - A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

AU - Samal, Akshaya K.

AU - Zhu, Haibo

AU - Harb, Moussab

AU - Sangaru, Shiv Shankar

AU - Anjum, Dalaver H.

AU - Hedhili, Mohamed N.

AU - Saih, Youssef

AU - Basset, Jean Marie

PY - 2017

Y1 - 2017

N2 - A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

AB - A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB?C2H5)3H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol.

UR - http://www.scopus.com/inward/record.url?scp=85026654497&partnerID=8YFLogxK

U2 - 10.1039/c6cy02187e

DO - 10.1039/c6cy02187e

M3 - Review article

AN - SCOPUS:85026654497

SN - 2044-4753

VL - 7

SP - 581

EP - 586

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 3

ER -

A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh & Ir) catalysts for efficient hydrogenolysis of ester

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