@article{b5ef1d98075f4364a7754dbf1269ffb5,
title = "A diamino-functionalized silsesquioxane pillared graphene oxide for CO2capture",
abstract = "In the race for viable solutions that could slow down carbon emissions and help in meeting the climate change targets a lot of effort is being made towards the development of suitable CO2adsorbents with high surface area, tunable pore size and surface functionalities that could enhance selective adsorption. Here, we explored the use of silsesquioxane pillared graphene oxide for CO2capture; we modified silsesquioxane loading and processing parameters in order to obtain pillared structures with nanopores of the tailored size and surface properties to maximize the CO2sorption capacity. Powder X-ray diffraction, XPS and FTIR spectroscopies, thermal analysis (DTA/TGA), surface area measurements and CO2adsorption measurements were employed to characterize the materials and evaluate their performance. Through this optimisation process, materials with good CO2storage capacities of up to 1.7/1.5 mmol g-1at 273 K/298 K in atmospheric pressure, were achieved.",
author = "Eleni Thomou and Viktoria Sakavitsi and Angeli, {Giasemi K.} and Konstantinos Spyrou and Froudas, {Konstantinos G.} and Diamanti, {Evmorfia K.} and Romanos, {George E.} and Karanikolos, {Georgios N.} and Trikalitis, {Pantelis N.} and Dimitrios Gournis and Petra Rudolf",
note = "Funding Information: The authors thank Oreste de Luca for the useful discussions, Laura Buis for help with preliminary experiments for this project and Juur van Dijken for the TGA measurements. ET was financially supported by the Hellenic Foundation for Research and Innovation (HFRI) and the General Secretariat for Research and Technology (GSRT), under the HFRI PhD Fellowship grant (GA. No. 1829) and by the Ubbo Emmius programme of the University of Groningen. Financial support by the Abu Dhabi National Oil Company R&D division (project RDProj.018-GP), by the Khalifa University (RC2-2019-007) and by the Advanced Materials Research Program of the Zernike National Research Centre under the Bonus Incentive Scheme (BIS) of the Dutch Ministry for Education, Culture and Science are also greatly appreciated. Funding Information: The authors thankOreste deLuca for theuseful discussions, Laura Buis for help with preliminary experiments for this project and Juur van Dijken for the TGA measurements. ET was nancially supported by the Hellenic Foundation for Research and Innovation (HFRI) and the General Secretariat for Research and Technology (GSRT), under the HFRI PhD Fellowship grant (GA. No. 1829) and by the Ubbo Emmius programme of the University of Groningen. Financial support by the Abu Dhabi National Oil Company R&D division (project RDProj.018-GP), by the Khalifa University (RC2-2019-007) and by the Advanced Materials Research Program of the Zernike National Research Centre under the Bonus Incentive Scheme (BIS) of the Dutch Ministry for Education, Culture and Science are also greatly appreciated. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = apr,
day = "13",
doi = "10.1039/d1ra00777g",
language = "British English",
volume = "11",
pages = "13743--13750",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "Royal Society of Chemistry",
number = "23",
}