TY - JOUR
T1 - 1H-Pyrazole-4-carboxylic acid-based metal–organic frameworks: Multifaceted materials
T2 - Coordination Chemistry Reviews
AU - Kumar Gupta, R.
AU - Kallem, P.
AU - Luo, G.-G.
AU - Cui, P.
AU - Wang, Z.
AU - Banat, F.
AU - Tung, C.-H.
AU - Sun, D.
N1 - Export Date: 11 January 2024; Cited By: 1; Correspondence Address: D. Sun; School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China; email: [email protected]; CODEN: CCHRA
PY - 2023
Y1 - 2023
N2 - Metal-organic frameworks (MOFs), consisting of metal ions or clusters coordinated with organic ligands, are a class of crystalline materials that have garnered widespread prominence recently due to their unique and tunable properties, forming extended 3D frameworks with well-defined porous structures. Their exceptional chemical and structural properties have captured the attention of researchers worldwide, making them an exciting avenue for developing innovative materials with diverse applications. In particular, MOFs containing ligands with carboxylic acid and N-containing moieties hold great promise for designing novel architectures suitable for various applications. The engineered flexibility and host–guest interaction chemistry of these MOFs make them excellent candidates for pioneering materials. This review presents an inclusive summary of the latest progress in pyrazolate carboxylate MOF design, focusing on their applications in sensing, catalysis, drug delivery, and luminescence. We also introduce the synthetic process and synergistic effects of MOFs in execution. Finally, we briefly outline the obstacles, opportunities, and implications for future development in these areas. © 2023 Elsevier B.V.
AB - Metal-organic frameworks (MOFs), consisting of metal ions or clusters coordinated with organic ligands, are a class of crystalline materials that have garnered widespread prominence recently due to their unique and tunable properties, forming extended 3D frameworks with well-defined porous structures. Their exceptional chemical and structural properties have captured the attention of researchers worldwide, making them an exciting avenue for developing innovative materials with diverse applications. In particular, MOFs containing ligands with carboxylic acid and N-containing moieties hold great promise for designing novel architectures suitable for various applications. The engineered flexibility and host–guest interaction chemistry of these MOFs make them excellent candidates for pioneering materials. This review presents an inclusive summary of the latest progress in pyrazolate carboxylate MOF design, focusing on their applications in sensing, catalysis, drug delivery, and luminescence. We also introduce the synthetic process and synergistic effects of MOFs in execution. Finally, we briefly outline the obstacles, opportunities, and implications for future development in these areas. © 2023 Elsevier B.V.
KW - 1H-Pyrazole-4-carboxylic acid
KW - Applications
KW - Crystal structure
KW - Metal-organic framework
KW - Mixed metal MOFs
KW - Organic linker
U2 - 10.1016/j.ccr.2023.215436
DO - 10.1016/j.ccr.2023.215436
M3 - Article
SN - 0010-8545
VL - 497
JO - Coord. Chem. Rev.
JF - Coord. Chem. Rev.
ER -